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In contrast, the 5-membered ring compounds -lipoic acid, -lipoamide, and 4-methyl-1,2-dithiolane-4-carboxamide (4-Me-dithiolane-CONH 2 ) yielded k 2 values of (1.5 0.2) 10 8 , (9.6 1.3) 10 7 and (7.7 1.1) 10 6 M 1 s 1 , respectively, with these being up to 20,000-fold higher than for the acyclic disulfides (Figs 2 and 3)

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